Edelstahl Eegeschaften

Exekutiv Resumé

Edelsteng are iron-based alloys defined by their ability to form and maintain a thin, Selbstheilende Chromoxid (Cr₂O₃) passiv Film.

This passive film — established when chromium content reaches roughly ≥10.5 wt% — is the foundation of their corrosion resistance and makes stainless steel distinct from plain carbon steels.

By adjusting alloying (Nt, An, Moien, N, Vun, Nb, etc.) a Mikrostruktur (austenitesch, frritesch, MARTENNESSITION, duplex, Nidderschlag-härt), engineers obtain a broad palette of combinations of corrosion performance, Staang, Zougankheet, fabricability and appearance.

1. What is stainless steel?

Defininitioun. Stainless steel is an iron-based alloy containing sufficient chromium (nominally ≥10.5 wt%) to form a continuous, protective chromium-oxide (Cr₂O₃) passive layer in oxygenated environments.

That passive film is thin (nm scale), self-repairing when oxygen is present, and is the fundamental basis for the material’s corrosion resistance.

Core Alloying Elements and Their Functions

• Chrogium (Nt, 10.5%-30%): The most critical element. At sufficient concentrations, Cr reacts with oxygen to form a dense, adherent Cr₂O₃ passive film (2–5 nm thick) that blocks corrosive media from attacking the iron matrix.
  Higher Cr content enhances general corrosion resistance but may increase brittleness if not balanced with other elements.
• Nickel (An, 2%-22%): Stabilizes the austenitic phase (face-zentréiert Kubik, FCC) bei Raumtemperatur, improving ductility, Zougankheet, an Deldbarkeet.
  Ni also enhances resistance to stress corrosion cracking (Scomme SMC) in chloride environments and low-temperature toughness (prevents brittle fracture below 0℃).
• Moybdsum (Moien, 0.5%-6%): Significantly improves resistance to pitting and crevice corrosion (besonnesch an chlorid-räich Ëmfeld) by increasing the passive film’s stability.
  Mo forms molybdenum oxide (MoO₃) to repair local film damage, making it essential for marine and chemical applications.
• Titanium (Vun) and Niobium (Nb, 0.1%–0.8%): Carbide stabilizers. They preferentially combine with carbon (C ') to form TiC or NbC,
  preventing the formation of Cr₂₃C₆ at grain boundaries during welding or high-temperature service—this avoids “chromium depletion” and subsequent intergranular corrosion (IGC).
• Manganese (MN-, 1%-15%): A cost-effective alternative to Ni for austenite stabilization (Z.B., 200-Serie STAINLESS Stol).
  Mn improves strength but may reduce corrosion resistance and toughness compared to Ni-bearing grades.
• Karkbelaéierung (C ', 0.01%-1,2%): Influences hardness and strength. Low C content (≤0,03%, L-grade) minimizes carbide formation and IGC risk; high C content (≥0.1%, martensitic grades) enhances hardenability via heat treatment.

Microstructural Classification and Key Characteristics

Austenitescht Edelstol (300-Serie, 200-Serie)

• Konwäertaarbecht: Héich Cr (16%–26%), An (2%-22%) or Mn, niddereg C (≤0.12%). Typical grades: 304 (18Cr-8ni), 316 (18Cr-10ni-2mo), 201 (17Cr-5Ni-6Mn).
• Microstruktur: Ganz austenitesch (FCC) bei Raumtemperatur, net magnetesch (except after cold working).
• Core Trait: Exzellent Kanidabilitéit, Zougankheet (even at cryogenic temperatures down to -270℃), an Deldbarkeet; balanced corrosion resistance.

Ferritic STAINLESS Stol (400-Serie)

• Konwäertaarbecht: Héich Cr (10.5%-27%), niddereg C (≤0.12%), no or minimal Ni. Typical grades: 430 (17Nt), 446 (26Nt).
• Microstruktur: Ferritesch (Kierperzenter Kubik, BCC) at all temperatures, magnetesch.
• Core Trait: Kascht effektiv, good general corrosion resistance, and oxidation resistance at high temperatures (up to 800℃); limited ductility and weldability.

Martensitic Edelstol (400-Serie, 500-Serie)

• Konwäertaarbecht: Medium Cr (11%-17%), high C (0.1%-1,2%), niddereg Ni. Typical grades: 410 (12Nt-0.15C '), 420 (13Nt-0.2C '), 440C ' (17Cr-1.0C).
• Microstruktur: MARTENNESSITION (body-centered tetragonal, BCT) nom Ofkillen an Tempering; magnetesch.
• Core Trait: Héich Hardness a Verschleißbeständegkeet (HRC 50–60 after heat treatment); moderéiert Korrosioun Resistenz.

Duplex Edelstol (2205, 2507)

• Konwäertaarbecht: Balanced austenitic-ferritic phases (50%±10% each), high Cr (21%-27%), An (4%–7%), Moien (2%-4%), N (0.1%-0,3%). Typical grades: 2205 (22Cr-5Ni-3Mo), 2507 (25Cr-7Ni-4Mo).
• Microstruktur: Dual-phase (FCC + BCC), magnetesch.
• Core Trait: Superior strength (twice that of austenitic grades) and resistance to SCC, Paéierung, and crevice corrosion; suitable for harsh marine and chemical environments.

Nidderschlag-Hardening (PH) Edelstol (17-4PH, 17-7PH)

• Konwäertaarbecht: Nt (15%-17%), An (4%–7%), CU- (2%-5%), Nb (0.2%–0.4%). Typical grade: 17-4PH (17Cr-4Ni-4Cu-Nb).
• Microstruktur: Martensitic or austenitic base with precipitates (Cu-rich phases, NbC) after aging treatment.
• Core Trait: Ultra-héich Kraaft (tensil Stäerkt >1000 MPa MPa) a gutt corrosion Resistenz; used in high-load aerospace and medical applications.

2. Core Performance: Korrosioun Resistenz

Corrosion resistance is the defining property of stainless steel, rooted in the passive film’s stability and alloying element synergies. Different grades exhibit distinct resistance to specific corrosion mechanisms.

Passive Film Mechanism and General Corrosion Resistance

The Cr₂O₃ passive film forms spontaneously in oxygen-containing environments (Stonn, d'Waassermonn) and is self-healing—if damaged (Z.B., kraazt), Cr in the matrix rapidly reoxidizes to repair the film.
Allgemeng Korrosioun (uniform oxidation) occurs only when the film is destroyed, such as in strong reducing acids (Hyddholsy Sorid) or high-temperature reducing atmospheres.

• Austenitesch Grad (304, 316): Resist general corrosion in atmospheric, fresh-water, and mild chemical environments. 316 outperforms 304 in chloride-rich media due to Mo addition.
• Ferritic Grad (430): Good general corrosion resistance in air and neutral solutions but susceptible to pitting in high-chloride environments.
• Duplex Qualitéiten (2205): Exceptional general corrosion resistance, combining Cr’s film-forming ability with Mo’s pitting resistance.

Specific Corrosion Types and Grade Adaptability

Pitting a Spuerkorrosioun

Pitting corrosion occurs when chloride ions (CL⁻) penetrate local defects in the passive film, forming small, deep corrosion pits.
Crevice corrosion is similar but localized in narrow gaps (Z.B., weld seams, fastener interfaces) where oxygen depletion accelerates corrosion.

• Key Influencing Elements: Mo and N significantly improve resistance—each 1% Mo addition reduces the critical pitting temperature (0 ugemol) by ~10℃.
  316 (CPT ≈ 40℃) outperforms 304 (CPT ≈ 10℃); 2507 duplex steel (CPT ≈ 60℃) is ideal for seawater applications.
• Preventive Measures: Use Mo-bearing grades, avoid crevice designs, and perform passivation treatments (nitric acid immersion) to enhance film integrity.

Intergrantular Korrosioun (IGC)

IGC arises from chromium depletion at grain boundaries: during welding or high-temperature service (450-850 ℃), carbon combines with Cr to form Cr₂₃C₆, leaving a Cr-depleted zone (Nt < 10.5%) that loses passivity.

• Resistant Grades: L-grades (304L, 316L, C ≤ 0.03%), stabiliséiert Qualitéiten (321 with Ti, 347 with Nb), and duplex grades (niddereg C + N stabilization).
• Mitigéieren: Post-Schweiß Wärmebehandlung (solution annealing at 1050–1150℃) to dissolve Cr₂₃C₆ and redistribute Cr.

Stress korrosion Cracking (Scomme SMC)

SCC occurs under the combined action of tensile stress and corrosive media (Z.B., Chorlungsmëttel, caustic solutions), leading to sudden brittle fracture.
Austenitesch Grad (304, 316) are susceptible to SCC in hot chloride environments (>60℃), while ferritic and duplex grades exhibit higher resistance.

• Resistant Grades: 2205 duplex steel, 430 ferritic steel, and PH grades (17-4PH).
• Mitigéieren: Reduce tensile stress (Stress Relief annealing), use low-Cl⁻ environments, or select duplex grades.

High-temperature and oxidation resistance

Oxidation resistance improves with Cr and Si; high-Cr ferritics (Z.B., 446 with ≈25–26% Cr) resist oxidation to ~800 °C. Austenitics like 310S (≈25% Cr, 20% An) are used for oxidation resistance up to ~1 000 ° C.
For continuous high-temperature strength or carburizing atmospheres, select purpose-designed heat-resistant alloys or Ni-base superalloys.

3. Mechanesch Eegeschafte

Stainless steel’s mechanical properties vary widely by microstructure and heat treatment, enabling customization for load-bearing, wear-resistent, or cryogenic applications.

Mechanical snapshot (talesch, rangéiert):

DUTSILITÉIT AN ZËNNNESS

• Austenitesch Grad: Exzellent Kanidabilitéit (elongation at break 40%–60%) an Zähegkeet (notch impact toughness Akv > 100 J bei Raumtemperatur).
  They retain toughness at cryogenic temperatures (Z.B., 304L Akv > 50 J at -200℃), suitable for LNG storage and cryogenic vessels.
• Ferritic Grad: Moderate ductility (elongation 20%–30%) but poor low-temperature toughness (brittle transition temperature ~0℃), limiting use in cold environments.
• Martensitic grades: Niddereg Diditéit (elongation 10%–15%) and toughness in the quenched state; tempering improves toughness (Akv 30–50 J) but reduces hardness.
• Duplex Qualitéiten: Balanced ductility (elongation 25%–35%) an Zähegkeet (Waasser > 80 J bei Raumtemperatur), with good low-temperature performance (brittle transition temperature < -40℃).

Middegkeet Resistenz

Fatigue resistance is critical for components under cyclic loads (Z.B., Schëffster, Quellen).
Austenitesch Grad (304, 316) have moderate fatigue strength (200–250 MPa, 40% of tensile strength) am annealed Staat; cold working increases fatigue strength to 300–350 MPa but raises sensitivity to surface defects.
Duplex Qualitéiten (2205) exhibit higher fatigue strength (300–380 MPa) due to their dual-phase structure, while PH grades (17-4PH) reach 400–500 MPa after aging.
Uewerfläch Behandlungen (Schoss peening, passivatioun) further enhance fatigue life by reducing stress concentrations and improving film stability.

4. Thermesch an elektresch Eegeschaften

Thermal properties

• Wärmeleitung (20 ° C): 304 ≈ 16 W·m⁻¹·K⁻¹; 316 ≈ 15 W·m⁻¹·K⁻¹; 430 ≈ 25–28 W·m⁻¹·K⁻¹. Stainless steels conduct heat much less effectively than carbon steel or aluminium.
• Koeffizient vun der thermescher Expansioun (20-100 ° C): Austenitics ≈ 16–17 ×10⁻⁶ K⁻¹; ferritics ≈ 10–12 ×10⁻⁶ K⁻¹; duplex ≈ 13–14 ×10⁻⁶ K⁻¹.
  Austenitics’ higher CTE leads to larger thermal movements and greater welding distortion risks.
• Héich Temperatur Kraaft: Austenitics retain strength at moderate temperatures; specialized grades (310S, heat-resistant ferritics) extend maximum use temperature. For continuous creep applications, choose creep-resistant steels or Ni-based alloys.

Elektresch Eegeschafte

Stainless steel is a moderate electrical conductor, with resistivity higher than copper and aluminum but lower than non-metallic materials.
Austenitesch Grad (304: 72 × 10⁻⁸ Ω·m) have higher resistivity than ferritic grades (430: 60 × 10⁻⁸ Ω·m) due to alloying element additions.
Its electrical conductivity is not suitable for high-efficiency conductors (dominated by copper/aluminum) but suffices for grounding rods, Elektresch Ariichtungen, and low-current components where mechanical strength and corrosion resistance are prioritized.

5. Veraarbechtung Leeschtung

Stainless steel’s processability (Schweißen, formeg, Maach) is critical for industrial manufacturing, with significant differences across grades.

Schweess Leeschtung

Weldability depends on microstructure, Kuelestoff Inhalt, and alloying elements:

• Austenitesch Grad (304, 316): Excellent weldability via arc welding, gas welding, an Laser Schweess.
  Low C grades (304L, 316L) and stabilized grades (321, 347) avoid IGC; post-weld passivation enhances corrosion resistance.
• Ferritic Grad (430): Poor weldability due to grain coarsening and brittleness in the heat-affected zone (Seum). Welding requires low heat input and preheating (100-200 ℃) to reduce HAZ cracking.
• Martensitic grades (410): Mëttelméisseg Schweessbarkeet. High C content causes HAZ hardening and cracking; virhëtzen (200-300 ℃) and post-weld tempering (600–700℃) obligatoresch sinn.
• Duplex Qualitéiten (2205): Good weldability but requires strict heat control (interpass Temperatur < 250℃) to maintain phase balance (50% austenite/ferrite). Post-Schweiß Léisung annealing (1050–1100℃) restauréiert corrosion Resistenz.

Forming Performance

Formability is linked to ductility and work hardening rate:

• Austenitesch Grad: Excellent formability due to high ductility and low work hardening rate.
  They can be deep-drawn, gestempelt, Beroun, and rolled into complex shapes (Z.B., 304 for food cans, architektonescht Brieder).
• Ferritic Grad: Moderate formability but prone to cracking during cold forming due to low ductility; warm forming (200-300 ℃) improves workability.
• Martensitic grades: Poor cold formability (niddereg Duktilitéit); forming is typically performed in the annealed state, gefollegt vun Ausschlëss an Tempering.
• Duplex Qualitéiten: Good formability (ähnlech zu 304) but requires higher forming force due to higher strength.

Machining Leeschtung

Machinability is influenced by hardness, Zougankheet, and chip formation:

• Austenitesch Grad: Poor machinability due to high toughness, Aarbecht harding, and chip adhesion to cutting tools. Machining requires sharp tools, low feed rates, and cutting fluids to reduce wear.
• Ferritic Grad: Moderate machinability, better than austenitic grades but worse than carbon steel.
• Martensitic grades: Good machinability in the annealed state (HB 180–220); hardening increases difficulty, requiring cemented carbide tools.
• PH grades: Moderate machinability in the solution-annealed state; aging hardens the material, making post-aging machining impractical.

6. Functional Properties and Special Applications

Beyond core performance, stainless steel’s functional properties (Biokompatibilitéit, Uewerfläch fäerdeg, magnetesch Eegeschaften) expand its application scope.

Biokompatibilitéit

Austenitesch Grad (316L, 316LVM) and PH grades (17-4PH) are biocompatible—they are non-toxic, non-irritating, and resistant to bodily fluids (blood, tissue).

316LVM (low carbon, vacuum melted) is used for surgical implants (bone plates, schrauwen Schrauwen, stents) due to its high purity and corrosion resistance in physiological environments.

Surface modifications (poléieren, electrochemical etching) further enhance biocompatibility by reducing bacterial adhesion.

Surface Properties and Aesthetics

Stainless steel’s surface can be tailored for aesthetics and functionality:

• Mechanesch Ofschloss: 2Elz, Nr 4 (gebastelt), BA (bright annealed), Spigel. Choose finish for intended aesthetic and cleanability.
• Elektropolesch: improves surface smoothness and corrosion resistance; commonly used in medical/food equipment.
• Chemesch Passivatioun: nitric or citric acid treatments remove free iron and augment the passive layer, improving corrosion resistance for food and medical applications.
• Coloration & zezeechnen: PVD or organic coatings can add color or additional protection; adhesion requires proper surface prep.

Magnéitesch Eegeschaften

Magnetism is determined by microstructure:

• Austenitesch Grad: Non-magnetic in the annealed state; cold working induces weak magnetism (due to martensitic transformation) but does not affect corrosion resistance.
• Ferritesch, MARTENNESSITION, and duplex grades: Magnéitesch, suitable for applications requiring magnetic responsiveness (Z.B., magnetic separators, sensor components).

7. Typical applications by family

• Entsteet (304/316): Liewensmëttelveraarbechtung, architectural cladding, chemesch Planz, kryogenic.
• Ferritesch (430/446): dekorative Trimm, automotive exhausts (446 high-temp), Apparater.
• MARTENNESSITION (410/420/440C '): Besteck, d'Ventil, Schëffster, zouzedrécken Deeler.
• Duplexex (2205/2507): UeleP & Gas (Sauer Service), Mierwaasser Systemer, chemical process equipment.
• PH (17-4PH): aerospace actuators, héich-Kraaft fasteners, applications demanding high strength with moderate corrosion resistance.

8. Comparison with Competing Materials

Material selection requires balancing mechanesch Leeschtung, Korrosioun Resistenz, gewun Du, thermal behavior, fabrizéieren Charakteristiken, an an life-cycle cost.

The comparison below focuses on stainless steel versus the most commonly considered metallic alternatives in engineering practice.

9. Conclusioun

Stainless steels are a versatile materials family that combines corrosion resistance, mechanical performance and aesthetic flexibility.

Successful use depends on aligning grade, microstructure and finish with the service environment and manufacturing process.

Use PREN and validated corrosion tests as screening tools for chloride environments; control fabrication heat history and surface condition; require MTRs and first-article corrosion/ mechanical qualification for critical systems.

When properly specified and processed, stainless steels deliver long service life and competitive life-cycle economics.

 

Faqs

Ass 316 always better than 304?

Net ëmmer. 316’s Mo content provides materially better pitting resistance in chloride environments; but for non-chloride indoor applications 304 is usually adequate and more economical.

What PREN value should I target for seawater service?

Target PREN ≥ 35 for moderate seawater exposure; for splash or warm seawater consider PREN ≥ 40+ (duplex or superaustenitics). Always validate with site-specific testing.

How do I avoid intergranular corrosion after welding?

Benotzt niddereg-Kuelestoff (L) oder stabiliséiert Qualitéiten, minimize time in the sensitization range, or perform solution annealing and pickling when practical.

When to choose duplex instead of austenitic stainless?

Choose duplex when you need greater strength and improved chloride/pitting and SCC resistance at a lower life-cycle cost than superaustenitics—common in oil & Gas, desalination and heat-exchanger applications.